It's not exactly icing on a cake, but it could be icing on a lake. A new paper by scientists on NASA's Cassini mission finds that blocks of hydrocarbon ice might decorate the surface of existing lakes and seas of liquid hydrocarbon on Saturn's moon Titan. The presence of ice floes might explain some of the mixed readings Cassini has seen in the reflectivity of the surfaces of lakes on Titan.
"One of the most intriguing questions about these lakes and seas is whether they might host an exotic form of life," said Jonathan Lunine from Cornell University in Ithaca, New York. "And the formation of floating hydrocarbon ice will provide an opportunity for interesting chemistry along the boundary between liquid and solid, a boundary that may have been important in the origin of terrestrial life."
Titan is the only other body besides Earth in our solar system with stable bodies of liquid on its surface. But while our planet's cycle of precipitation and evaporation involves water, Titan's cycle involves hydrocarbons like ethane and methane. Ethane and methane are organic molecules, which scientists think can be building blocks for the more complex chemistry from which life arose. Cassini has seen a vast network of these hydrocarbon seas cover Titan's northern hemisphere, while a more sporadic set of lakes bejewels the southern hemisphere.
Up to this point, Cassini scientists assumed that Titan lakes would not have floating ice because solid methane is denser than liquid methane, and it would sink. But the new model considers the interaction between the lakes and the atmosphere, resulting in different mixtures of compositions, pockets of nitrogen gas, and changes in temperature. The result, scientists found, is that winter ice will float in Titan's methane- and ethane-rich lakes and seas if the temperature is below the freezing point of methane — –297° Fahrenheit (–183° Celsius). The scientists realized that all the varieties of ice they considered would float if they were composed of at least 5 percent "air," which is an average composition for young sea ice on Earth; "air" on Titan has significantly more nitrogen than Earth air and almost no oxygen.
If the temperature drops by just a few degrees, the ice will sink because of the relative proportions of nitrogen gas in the liquid versus the solid. Temperatures close to the freezing point of methane could lead to both floating and sinking ice — that is, a hydrocarbon ice crust above the liquid and blocks of hydrocarbon ice on the bottom of the lake bed. Scientists haven't entirely figured out what color the ice would be, though they suspect it would be colorless as it is on Earth, perhaps tinted reddish-brown from Titan's atmosphere.
"We now know it's possible to get methane- and ethane-rich ice freezing over on Titan in thin blocks that congeal together as it gets colder — similar to what we see with Arctic Sea ice at the onset of winter," said Jason Hofgartner from Cornell University in Ithaca, New York. "We'll want to take these conditions into consideration if we ever decide to explore the Titan surface some day."
Cassini's radar instrument will be able to test this model by watching what happens to the reflectivity of the surface of these lakes and seas. A hydrocarbon lake warming in the early spring thaw, as the northern lakes of Titan have begun to do, may become more reflective as ice rises to the surface. This would provide a rougher surface quality that reflects more radio energy back to Cassini, making it look brighter. As the weather turns warmer and the ice melts, the lake surface will be pure liquid, and it will appear to the Cassini radar to darken.
"Cassini's extended stay in the Saturn system gives us an unprecedented opportunity to watch the effects of seasonal change at Titan," said Linda Spilker from NASA's Jet Propulsion Laboratory in Pasadena, California. "We'll have an opportunity to see if the theories are right."